半岛bd体育手机客户端 说明

应用

Catalyst for:

• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
• Solvent-free Heck reactions

Cocatalyst in:

• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
• Rhodium-catalyzed hydrogenation reactions
• Platinum-catalyzed allylation reactions

包装

1 g in glass bottle

基本信息

线性分子式	(ClC6H4)3P
分子量	365.62
EC 号	214-596-7
MDL编号	MFCD00013639
PubChem化学物质编号	24854999
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	95%
形式	powder
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand reaction type: Cross Couplings
mp	100-103 ℃ (lit.)
官能团	phosphine
SMILES string	Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3
InChI	1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChI key	IQKSLJOIKWOGIZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves