半岛bd体育手机客户端 说明
应用
Difluoromethyl azide dissolved in DME is a conveniently handled form of this rare fluorinated building block, opening a straightforward access to regioisomerically pure N-difluoromethyl triazoles using the conventional copper catalyzed alkyne-azide cycloaddition or the enamine-mediate azide-ketone [3+2] cycloaddition
其他说明
Azidoperfluoroalkanes: Synthesis and Application in Copper(I)-Catalyzed Azide–Alkyne Cycloaddition
Enamine-Mediated Azide-Ketone [3 + 2] Cycloaddition of Azidoperfluoroalkanes
基本信息
线性分子式 | CHF2N3 |
MDL编号 | MFCD24454794 |
半岛bd体育手机客户端 性质
形式 | liquid |
浓度 | (1.2 M in DME) |
SMILES string | [N-]=[N+]=NC(F)F |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H225 - H315 - H332 - H360FD |
预防措施声明 | P202 - P210 - P233 - P303 + P361 + P353 - P304 + P340 + P312 - P308 + P313 |
危险分类 | Acute Tox. 4 Inhalation - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 |
补充剂危害 | EUH019 |
储存分类代码 | 3 - Flammable liquids |
WGK | WGK 3 |
闪点(F) | 26.6 °F |
闪点(C) | -3 ℃ |
Sigma-Aldrich