半岛bd体育手机客户端 说明

一般描述

5-Isopropyl-1,3-cyclohexanedione is a cyclic 1,3-diketone. It can be prepared by condensation of isobutylideneacetone with ethyl malonate. 5-Isopropyl-1,3-cyclohexanedione on methylation with methyl iodide yields 5-isopropyl-2-methyl-1,3-cyclohexanedione. A multistep-synthesis of 5-isopropyl-1,3-cyclohexanedione involving aldol condensation, Dieckmann-type annulation, ester hydrolysis and decarboxylation is reported.

应用

5-Isopropyl-1,3-cyclohexanedione may be used as starting reagent for the synthesis of carvotanacetone analogs. It may be used in the preparation of monocyclic terepenes. It may be used in the synthesis of 2H-pyrans, via reaction with α,β-unsaturated aldehydes.

包装

5 g in poly bottle

基本信息

线性分子式	(CH3)2CHC6H7(=O)2
分子量	154.21
MDL编号	MFCD00150873
PubChem化学物质编号	24861163
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	99% (GC)
mp	63-65 ℃ (lit.)
运输	dry ice
SMILES string	[H]O[H].CC(C)C1CC(=O)CC(=O)C1
InChI	1S/C9H14O2.H2O/c1-6(2)7-3-8(10)5-9(11)4-7;/h6-7H,3-5H2,1-2H3;1H2
InChI key	JYJVWRORYGGPHA-UHFFFAOYSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)