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1 M Biphenyl in THF

品牌
Sigma-Aldrich
货号
916803
规格纯度
a precursor solution to prepare the prelithiation/presodiation reagent for disordered carbon, SiO, Sn, Sb, P, and S electrodes
价格
1532.22 *本价格含增值税费
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半岛bd体育手机客户端 名称:
1 M Biphenyl in THF
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

This product is biphenyl (Bp) solution in anhydrous THF (1 mol/L) is a precursor reagent that could be easily handled to prepare prelithiation or presodiation reagent. By direct reaction of Li metal, it forms a strong reducing reagent of Li-Bp. The resulting Li-Bp/THF reagent has the redox potential of 0.41 V vs. Li/Li+, which is applicable to prelithiate most of the active materials for Li ion batteries, such as Sn, Sb, P, S, SiO and other metal oxide. On the other hand, a presodiation reagent can be prepared by reacting Bp/THF solution with Na metal. Na-Bp/THF reagent can be used to presodiate hard carbon, a promising anode material in Na ion batteries.

制备说明

Suggested Directions for use:

  • Step 1 Preparation of Prelithiation/presodiation reagent
Before use of Li metal, scrub the lithium surface to remove oxide and nitride layers.
To prepare 1 M Li-Bp/THF reagent, > 0.07 g of Li metal is added into every 10 ml of 1 M BP/THF solution
To prepare 1 M Na-Bp/THF reagent, > 0.23 g of Na metal is added into every 10 ml of 1 M BP/THF solution
  • Step 2 Prelithiation/presodiation of electrodes
For a 1 cm diameter electrode with 1-3 mg acitve material per cm 2, soak (10-60 min, times will vary with material) the electrode in ~0.5-1 mL of prelithiation/presodiation reagent. Discard the solution and then wash the electrode twice with THF. Longer prelithiation/presodiation time may cause electrode structure deformation, leading to a decreased discharge/charge capacity.

基本信息

经验(实验)分子式 C12H10
分子量 154.21
MDL编号 MFCD00003054

半岛bd体育手机客户端 性质

质量水平 100
浓度 1 M
储存温度 2-8℃

安全信息

象形图 GHS02GHS07GHS08GHS09
警示用语: Danger
危险声明 H225 - H302 - H315 - H319 - H335 - H336 - H351 - H411
预防措施声明 P210 - P273 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
危险分类 Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
补充剂危害 EUH018 - EUH019
储存分类代码 3 - Flammable liquids
WGK WGK 2
闪点(F) 1.4 °F
闪点(C) -17 ℃

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