半岛bd体育手机客户端 说明
应用
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine [Pybox] may be used as a chiral ligand in the copper-catalyzed enatioselective arylation ofN-arylated tetrahydroisoquinolines (THIQs) with arylboronic acids in the presence of a photoredox catalyst.
包装
2 g in glass bottle
500 mg in glass insert
基本信息
经验(实验)分子式 | C23H19N3O2 |
分子量 | 369.42 |
MDL编号 | MFCD01863585 |
PubChem化学物质编号 | 24873016 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
测定 | 98% |
旋光性 | [α]22/D 187°, c = 1 in methylene chloride |
mp | 171-175 ℃ (lit.) |
SMILES string | C1OC(=N[C@@H]1c2ccccc2)c3cccc(n3)C4=N[C@@H](CO4)c5ccccc5 |
InChI | 1S/C23H19N3O2/c1-3-8-16(9-4-1)20-14-27-22(25-20)18-12-7-13-19(24-18)23-26-21(15-28-23)17-10-5-2-6-11-17/h1-13,20-21H,14-15H2/t20-,21-/m0/s1 |
InChI key | HLHBIMJNCKZZQO-SFTDATJTSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich