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Tricyclohexylphosphine solution

三环己基磷 溶液

品牌
Sigma-Aldrich
CAS
2622-14-2
货号
455164
规格纯度
20 wt. % in toluene
价格
613.45 *本价格含增值税费
促销
服务
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数量
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半岛bd体育手机客户端 名称:
2622-14-2
Tricyclohexylphosphine solution
PCy 3
NSC 158657
三环己基磷 溶液
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Catalyst for:

  • Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
  • Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
  • Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
  • Synthesis of (-)-Exiguolide and its analogues
  • Allylation of zinc enolates

Reagent used as a ligand for a range of metal-catalyzed organic transformations.

包装

100, 500 g in glass bottle

基本信息

线性分子式 (C6H11)3P
分子量 280.43
Beilstein 957171
MDL编号 MFCD00003853
PubChem化学物质编号 24869033
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
浓度 20 wt. % in toluene
官能团 phosphine
SMILES string C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InChI 1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
InChI key WLPUWLXVBWGYMZ-UHFFFAOYSA-N

安全信息

象形图 GHS02GHS07GHS08
警示用语: Danger
危险声明 H225 - H304 - H315 - H319 - H335 - H336 - H361d - H373 - H412
预防措施声明 P210 - P273 - P301 + P310 - P303 + P361 + P353 - P305 + P351 + P338 - P331
危险分类 Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2
靶器官 Central nervous system
储存分类代码 3 - Flammable liquids
WGK WGK 3
闪点(F) 51.8 °F - closed cup
闪点(C) 11 ℃ - closed cup
个人防护装备 Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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