半岛bd体育手机客户端 说明

一般描述

tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence ofR-(salen)Co complex and water.

应用

tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol.

包装

10 g in glass bottle

基本信息

经验(实验)分子式	C9H20O2Si
分子量	188.34
MDL编号	MFCD02683555
PubChem化学物质编号	24874536

半岛bd体育手机客户端 性质

测定	98%
折射率	n 20/D 1.531 (lit.)
bp	195-197 ℃ (lit.)
密度	0.901 g/mL at 25 ℃ (lit.)
SMILES string	CC(C)(C)[Si](C)(C)OCC1CO1
InChI	1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3
InChI key	YANSSVVGZPNSKD-UHFFFAOYSA-N

安全信息

储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	158.0 °F - closed cup
闪点(C)	70 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)