硼烷二苯基膦复合物

品牌

Sigma-Aldrich

CAS

41593-58-2

货号

449563

包装型号

规格纯度

98%

价格

2979.89 元 *本价格含增值税费

促销

数量

- +

半岛bd体育手机客户端名称：

41593-58-2
Borane diphenylphosphine complex
(Diphenylphosphine)trihydroboron
硼烷二苯基膦复合物

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

应用

Reactant for:

Nucleophilic addition reactions (anion)
Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
Deprotonation reactions
Catalytic coupling with alkynyl bromides
Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

包装

5 g in glass bottle

基本信息

半岛bd体育手机客户端性质

质量水平	100
测定	98%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand reaction type: Reductions reagent type: reductant
bp	148-150 ℃/10 mmHg (lit.)
mp	47-50 ℃ (lit.)
官能团	phosphine
SMILES string	B.[H]P(c1ccccc1)c2ccccc2
InChI	1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
InChI key	XUFGOLYVDOBYLK-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H261
预防措施声明	P231 + P232 - P422
危险分类	Water-react. 2
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges