半岛bd体育手机客户端 说明

应用

Trifluoromethanesulfonic anhydride can be used in the preparation of azido sugars such as 6-azido fucose. It can also be used as a promoter for the Friedel-Crafts acylation of aromatic compounds with carboxylic acids in the absence of catalyst.
Tf2O in combination with:

• Diphenyl sulfoxide, forms an efficient promoter system for the activation of thioglycosides for glycosylation reactions.
• 2-chloropyridine, can be used for secondary amide activation.
• Potassium iodide, can effectively mediate the deoxygenation of sulfoxides to form sulfides.
• Hydrogen peroxide, for the selective oxidation of sulfanes to sulfoxides in the presence of oxidatively sensitive functional groups.

Tf2O can react with:

• Ketones in the presence of a base to form vinyl triflates.
• Magnesium alkoxides to form corresponding symmetrical or unsymmetrical ethers.
• Sodium azide for thein situpreparation of triflyl azide.

糖基化合成催化剂糖基化合成试剂
甘露三嗪甲基脲酸酯供体糖基化空间选择性合成试剂
异丙基羟基糖直接糖基化活化剂

包装

100 mL in glass bottle

其他说明

亲电子三氟甲磺酰基的来源。综述

基本信息

线性分子式	(CF3SO2)2O
分子量	282.14
Beilstein	1813600
EC 号	206-616-8
MDL编号	MFCD00000408
PubChem化学物质编号	329770073
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	200
蒸汽密度	5.2 (vs air)
蒸汽压	8 mmHg ( 20 ℃)
等级	purum
测定	≥98.0% (T)
形式	liquid
折射率	n 20/D 1.321 (lit.)
bp	81-83 ℃ (lit.)
密度	1.677 g/mL at 25 ℃ (lit.)
SMILES string	FC(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F
InChI	1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8
InChI key	WJKHJLXJJJATHN-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H272 - H302 - H314 - H335
预防措施声明	P210 - P220 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官	Respiratory system
补充剂危害	EUH014
储存分类代码	5.1B - Oxidizing hazardous materials
WGK	WGK 3
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter