Grubbs Catalyst^?M206

半岛bd体育手机客户端 说明

应用

• Bulky NHC ligand results in faster initiation than the Grubbs 2^ndGeneration Catalyst.
• Has enabled lower catalyst loadings in some applications.

Grubbs Catalyst ^?M2a SIPr is a second generation Grubb′s catalyst used to catalyze olefin metathesis which low catalyst loading. This is also used in synthesizing variety of highly active second generation fast-initiation Hoveyda type ruthenium catalysts.

包装

2 g in glass bottle
100 mg in clear glass bottle
500 mg in glass bottle

其他说明

Ruthenium-based catalysts for olefin metathesis

Grubbs Catalyst^?Technology for Olefin Metathesis by sigma-aldrich

法律信息

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through sigma-aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

基本信息

经验(实验)分子式	C52H77Cl2N2PRu
分子量	933.13
PubChem化学物质编号	329764471

半岛bd体育手机客户端 性质

mp	176-181 ℃
储存温度	2-8℃
SMILES string	C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)c4cccc(C(C)C)c4N5CCN(C5[Ru](Cl)(Cl)=Cc6ccccc6)c7c(cccc7C(C)C)C(C)C
InChI	1S/C27H39N2.C18H33P.C7H6.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-14,17-21H,15-16H2,1-8H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
InChI key	VWYWCKUDPDENIJ-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Warning
危险声明	H228
预防措施声明	P210
危险分类	Flam. Sol. 2
储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable