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Lithium (trimethylsilyl)acetylide solution

三甲基硅基乙炔锂

品牌
Sigma-Aldrich
CAS
54655-07-1
货号
335452
规格纯度
0.5 M in THF
价格
723.17 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
- +
半岛bd体育手机客户端 名称:
54655-07-1
Lithium (trimethylsilyl)acetylide solution
(Trimethylsilyl)ethynyllithium
三甲基硅烷基乙炔锂 溶液
三甲基硅基乙炔锂
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Reacts with halotriazines to produce conductive, anisotropic carbon-nitrogen materials.
Lithium (trimethylsilyl)acetylide can be used as a reagent:

  • In the transmetalation and nucleophilic displacement reactions.
  • To prepare propargylic alcohol derivatives by reacting with aldehydes and ketones.
  • To synthesize α,βynones by treating with Weinreb amide or with isoxazolidide.
  • Along with Grignard reagent to convert γ- and δ-thiolactams to thioiminium salts, which are employed as key intermediates to produce disubstituted pyrrolidines.

包装

4×25, 50, 500 mL in Sure/Seal?
The 25 mL Sure/Seal?bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律信息

Sure/Seal is a trademark of sigma-aldrich Co. LLC

基本信息

线性分子式 (CH3)3SiC≡CLi
分子量 104.15
Beilstein 3587411
MDL编号 MFCD00075059
PubChem化学物质编号 24860321
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
浓度 0.5 M in THF
密度 0.88 g/mL at 25 ℃
SMILES string [Li]C#C[Si](C)(C)C
InChI 1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
InChI key ZVXXEONXFWSCIZ-UHFFFAOYSA-N

安全信息

象形图 GHS02GHS05GHS07GHS08
警示用语: Danger
危险声明 H225 - H302 - H314 - H335 - H351
预防措施声明 P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
危险分类 Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官 Respiratory system
补充剂危害 EUH019
储存分类代码 3 - Flammable liquids
WGK WGK 3
闪点(F) -9.4 °F - closed cup
闪点(C) -23 ℃ - closed cup
个人防护装备 Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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