半岛bd体育手机客户端 说明

一般描述

2-Amino-4-chlorobenzenethiol reacts with aromatic aldehydes and cyclohexanecarboxaldehyde to afford the corresponding thiazole and thiazoline derivatives. It undergoes oxidation in the presence of 1-n-butyl-3-methylimidazolium methylselenite, [bmim][SeO₂(OCH₃)] to form the corresponding symmetrical disulfide.

应用

2-Amino-4-chlorobenzenethiol may be used in the synthesis of:

• 2,3-dihydro-1,5-benzothiazepin-4-(5H)-ones
• 8-chloro-1-azaphenothiazine
• 5-chloro-2-(4-methoxyphenyl)-2,3-dihydro-1,3,2-benzothiazaphosphole 2-sulfide

包装

5, 25 g in glass bottle

基本信息

线性分子式	H2NC6H3(Cl)SH
分子量	159.64
MDL编号	MFCD00792528
PubChem化学物质编号	24878564
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	200
测定	96%
mp	56-61 ℃ (lit.)
SMILES string	Nc1cc(Cl)ccc1S
InChI	1S/C6H6ClNS/c7-4-1-2-6(9)5(8)3-4/h1-3,9H,8H2
InChI key	NGIRMPARLVGMPX-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves