半岛bd体育手机客户端 名称：
15529-49-4
Tris(triphenylphosphine)ruthenium(II) Dichloride
Tris(triphenylphosphine)dichlororuthenium
Dichlorotris(triphenylphosphine)ruthenium(II)
Ruthenium(II)-tris(triphenylphosphine) dichloride
三(三苯基膦)二氯化钌(II)
三(三苯基膦)氯化钌(II)
三苯基膦氯化钌
三（三苯基膦）二氯钌
半岛bd体育手机客户端 介绍：
半岛bd体育手机客户端 说明
应用
Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize:
- Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3C-H bond activation of primary alcohols in the presence of Lewis acid.
- Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
- 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
- Vinyl chloride monomer by hydrochlorination reaction of acetylene.
RuCl
2(PPh
3)
3can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
包装
1, 5, 25 g in glass bottle
基本信息
| 线性分子式 |
[(C6H5)3P]3RuCl2 |
| 分子量 |
958.83 |
| Beilstein |
4935939 |
| EC 号 |
239-569-7 |
| MDL编号 |
MFCD00013077 |
| PubChem化学物质编号 |
24853394 |
| NACRES |
NA.22 |
半岛bd体育手机客户端 性质
| 质量水平 |
100 |
| 测定 |
97% |
| reaction suitability |
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation |
| SMILES string |
Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| InChI |
1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2 |
| InChI key |
WIWBLJMBLGWSIN-UHFFFAOYSA-L |
安全信息
| 储存分类代码 |
13 - Non Combustible Solids |
| WGK |
WGK 3 |
| 闪点(F) |
Not applicable |
| 闪点(C) |
Not applicable |
| 个人防护装备 |
dust mask type N95 (US), Eyeshields, Gloves |
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