半岛bd体育手机客户端 说明

一般描述

Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide.

应用

2-Amino-6-bromobenzothiazole may be used in the synthesis of the following

• 2-amino-6-arylbenzothiazole compounds:
• 6-p-tolylbenzo[d]thiazole-2-amine
• 6-(4chlorophenyl)benzo[d]thiazole-2-amine
• 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine
• 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine
• 6-phenylbenzo[d]thiazole-2-amine

It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO) ₂(L)(Cl)].

包装

1, 5, 25 g in glass bottle

基本信息

经验(实验)分子式	C7H5BrN2S
分子量	229.10
MDL编号	MFCD00152229
PubChem化学物质编号	24878338
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	97%
mp	213-217 ℃ (lit.)
SMILES string	Nc1nc2ccc(Br)cc2s1
InChI	1S/C7H5BrN2S/c8-4-1-2-5-6(3-4)11-7(9)10-5/h1-3H,(H2,9,10)
InChI key	VZEBSJIOUMDNLY-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 - H317 - H319
预防措施声明	P261 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Faceshields, Gloves