半岛bd体育手机客户端 说明
一般描述
1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
应用
用于全氟烷基化和 Vilsmeier 甲酰化反应。
包装
5, 25 mL in glass bottle
基本信息
| 经验(实验)分子式 | C13H25NSi |
| 分子量 | 223.43 |
| MDL编号 | MFCD00054932 |
| PubChem化学物质编号 | 24863531 |
| NACRES | NA.22 |
半岛bd体育手机客户端 性质
| 质量水平 | 100 |
| 测定 | 95% |
| 折射率 | n
|
| bp | 78 ℃/0.4 mmHg (lit.) |
| 密度 | 0.904 g/mL at 25 ℃ (lit.) |
| SMILES string | CC(C)[Si](C(C)C)(C(C)C)n1cccc1 |
| InChI | 1S/C13H25NSi/c1-11(2)15(12(3)4,13(5)6)14-9-7-8-10-14/h7-13H,1-6H3 |
| InChI key | FBQURXLBJJNDBX-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H302 + H332 - H319 |
| 预防措施声明 | P261 - P264 - P270 - P301 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 224.6 °F - closed cup |
| 闪点(C) | 107 ℃ - closed cup |
Sigma-Aldrich
m.cnreagent.com
