半岛bd体育手机客户端 说明

应用

(S)-(-)-Methylp-tolyl sulfoxide can be used as a nucleophilic reagent to synthesize:

• Optically active β-disulfoxides by reacting with arenesulfinic esters via formation of α-sulfinylcarbanion.
• α-substitutedN-hydroxylamines by treating with nitrones via preparation of (S)-(-)-methylp-tolyl sulfoxide anion.
• 2-O-benzyl-3,4-O-isopropylidene- L -erythrose by one-carbon homologation of 2,3-O-isopropylidene- L -glyceraldehyde.

包装

1 g in glass bottle

基本信息

线性分子式	CH3C6H4S(O)CH3
分子量	154.23
Beilstein	2324696
MDL编号	MFCD00151503
PubChem化学物质编号	24860755

半岛bd体育手机客户端 性质

质量水平	100
测定	99%
旋光性	[α]20/D ?145°, c = 2 in acetone
光学纯度	ee: 99% (HPLC)
mp	75-77 ℃ (lit.)
SMILES string	Cc1ccc(cc1)S(C)=O
InChI	1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3/t10-/m0/s1
InChI key	FEVALTJSQBFLEU-JTQLQIEISA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)