Tris(dibenzylideneacetone)dipalladium(0) ChemBeads

半岛bd体育手机客户端 说明

应用

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for C-C and C-N bond formation especially Suzuki, Heck coupling reaction

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:

• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
• Preparation of palladium triphenylphosphine carbonyl cluster complexes
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes

Catalyst for:

• Suzuki cross-coupling reactions
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation

其他说明

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

法律信息

Tris(dibenzylideneacetone)dipalladium(0) is Product of Umicore

Additional information available at www.pmc.umicore.com

基本信息

线性分子式	(C6H5CH=CHCOCH=CHC6H5)3Pd2
分子量	915.72
MDL编号	MFCD00013310

半岛bd体育手机客户端 性质

质量水平	100
测定	~5 wt.% loading of catalyst
形式	solid
储存温度	2-8℃
SMILES string	O=C(/C=C/c1ccccc1)/C=C/c2ccccc2.O=C(/C=C/c3ccccc3)/C=C/c4ccccc4.O=C(/C=C/c5ccccc5)/C=C/c6ccccc6.[Pd].[Pd]
InChI key	CYPYTURSJDMMMP-WVCUSYJESA-N

安全信息

象形图
警示用语：	Danger
危险声明	H317 - H350i - H412
预防措施声明	P201 - P202 - P273 - P280 - P302 + P352 - P308 + P313
危险分类	Aquatic Chronic 3 - Carc. 1B Inhalation - Skin Sens. 1
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable