半岛bd体育手机客户端 说明

一般描述

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by¹H,¹³C and¹⁵N NMR spectral data.

应用

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

其他说明

将醇轻度氧化成羰基的新型氧化剂

基本信息

经验(实验)分子式	C11H21N2O2
分子量	213.30
Beilstein	3546225
EC 号	423-840-3
MDL编号	MFCD00043593
PubChem化学物质编号	329747053
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	200
等级	purum
测定	≥98.0% (HPLC)
环保替代半岛bd体育手机客户端 得分	old score: 9 new score: 8 Find out more about DOZN? Scoring
环保替代半岛bd体育手机客户端 特性	Waste Prevention Safer Solvents and Auxiliaries Inherently Safer Chemistry for Accident Prevention Learn more about the Principles of Green Chemistry.
mp	143-145 ℃ (lit.) 143-146 ℃
环保替代半岛bd体育手机客户端 分类	Re-engineered
储存温度	2-8℃
SMILES string	CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
InChI	1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
InChI key	UXBLSWOMIHTQPH-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302
预防措施声明	P264 - P270 - P301 + P312 + P330 - P501
危险分类	Acute Tox. 4 Oral
储存分类代码	13 - Non Combustible Solids
WGK	WGK 1
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves