半岛bd体育手机客户端 说明
一般描述
2-Formylphenyl sulfofluoridate is an aryl fluorosulfate. It can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine. It undergoes Sonogashira coupling reaction with phenyl acetylene.
应用
The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.
包装
500 mg in glass bottle
其他说明
Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates
基本信息
经验(实验)分子式 | C7H5FO4S |
分子量 | 204.18 |
PubChem化学物质编号 | 329772674 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
描述 | Fp: >230°F |
形式 | liquid |
折射率 | n
|
密度 | 1.4545 g/mL at 25 ℃ |
SMILES string | O=S(OC1=C(C=O)C=CC=C1)(F)=O |
InChI | 1S/C7H5FO4S/c8-13(10,11)12-7-4-2-1-3-6(7)5-9/h1-5H |
InChI key | SUOCJDDQQKVIKZ-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H314 |
危险分类 | Skin Corr. 1B |
储存分类代码 | 8B - Non-combustible, corrosive hazardous materials |
WGK | WGK 3 |
闪点(F) | No data available |
闪点(C) | No data available |
Sigma-Aldrich