Palladium(II) chloride ChemBeads

半岛bd体育手机客户端 说明

一般描述

Palladium(II) chloride (PdCl₂) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl₂reacts withN,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF₄] or [bmim][PF₆] (where[bmim]⁺= 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
This product is part of a group of 5 products: CHEMBEADS. These materials are made by mixing a catalog product catalyst with glass beads.

应用

Palladium(II) chloride (PdCl₂) was used in the following studies:

• As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide.
• As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles.
• Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

其他说明

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

基本信息

经验(实验)分子式	Cl2Pd
分子量	177.33
MDL编号	MFCD00003558

半岛bd体育手机客户端 性质

测定	~4 wt.% loading of catalyst
质量水平	100
形式	solid
SMILES string	Cl[Pd]Cl
InChI	1S/2ClH.Pd/h2*1H;/q;;+2/p-2
InChI key	PIBWKRNGBLPSSY-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Danger
危险声明	H290 - H317 - H318 - H350i - H410
预防措施声明	P201 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类	Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1
储存分类代码	6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK	WGK 3