Palladium(II) Acetate ChemBeads

半岛bd体育手机客户端 说明

一般描述

Palladium(II) acetate is a homogenous oxidation catalyst. It participates in the activation of alkenic and aromatic compounds towards oxidative inter- and intramolecular nucleophilic reactions. Crystals of palladium(II) acetate have a trimeric structure, having symmetry D_3h. Each of the palladium atoms in the crystals are joined to the other two by double acetate bridges. Microencapsulation of palladium(II) acetate in polyurea affords polyurea-encapsulated palladium(II) acetate. It is a versatile heterogeneous catalyst for various phosphine-free cross-coupling reactions. It participates as catalyst in the Heck coupling reaction of pthalides with different alkenes.

应用

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for an intramolecular coupling of aryl bromides with alcohols giving 1,3-oxazepines. Preparation of cyclic ureas via palladium-catalyzed intramolecular cyclization.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

其他说明

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

基本信息

线性分子式	Pd(OCOCH3)2
MDL编号	MFCD00012453

半岛bd体育手机客户端 性质

测定	~4 wt.% loading of catalyst
质量水平	100
形式	solid
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction core: palladium reaction type: Heck Reaction core: palladium reaction type: Hiyama Coupling core: palladium reaction type: Negishi Coupling core: palladium reaction type: Sonogashira Coupling core: palladium reaction type: Stille Coupling core: palladium reaction type: Suzuki-Miyaura Coupling reagent type: catalyst

安全信息

象形图
警示用语：	Danger
危险声明	H317 - H318 - H410
预防措施声明	P261 - P272 - P273 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A
储存分类代码	11 - Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable