半岛bd体育手机客户端 说明
一般描述
DTBPF-Pd-G-3 is a versatile palladium precatalyst developed by Buchwald group. It is widely employed in various cross-coupling reactions involving the formation of C-C, C-N, C-O, C-F, C-CF3, and C-S bonds. Precatalysts effectively generate active catalytic species for use in various reactions.
应用
Pd precatalyst for cross-coupling. Buchwald Third Generation Palladium Precatalyst.
包装
1 g in glass bottle
250 mg in glass bottle
基本信息
经验(实验)分子式 | C39H57FeNO3P2PdS |
分子量 | 844.15 |
MDL编号 | MFCD28009169 |
PubChem化学物质编号 | 329768913 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
特点 | generation 3 |
reaction suitability | core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst reagent type: ligand |
杂质 | may contain 10-20% Di-μ-mesylbis[2′-(amino-N)[1,1′-biphenyl]-2-yl-C]dipalladium(II) (Aldrich Number762156) may contain 5-10% DTBPF (Aldrich Number695149) may contain 5-10% pentane |
mp | 87-150 ℃ (decomposition) |
官能团 | phosphine |
InChI | 1S/2C13H22P.C12H10N.CH4O3S.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h2*7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q;;;;;+1/p-1 |
InChI key | AGXLTHQKOWPGBX-UHFFFAOYSA-M |
安全信息
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich