半岛bd体育手机客户端 说明
应用
4-(Trifluoromethyl)benzenesulfonyl chloride may be used to synthesize β-arylated thiophenes and 2,5-diarylated pyrrolevia palladium catalyzed desulfitative arylation of thiophenes and pyrroles, respectively.
4-(Trifluoromethyl)benzenesulfonyl chloride andN-vinylpyrrolidinone in acetonitrile can undergo photo-irradiation with visible light in the presence of Ir(ppy)2(dtbbpy)PF6([4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III)hexafluorophosphate) and disodium phosphate to give the correspondingE-vinyl sulfone.
包装
1, 5 g in glass bottle
注意
低熔点固体
基本信息
线性分子式 | CF3C6H4SO2Cl |
分子量 | 244.62 |
Beilstein | 2113604 |
MDL编号 | MFCD00042422 |
PubChem化学物质编号 | 24880261 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
测定 | 97% |
mp | 30-34 ℃ (lit.) |
SMILES string | FC(F)(F)c1ccc(cc1)S(Cl)(=O)=O |
InChI | 1S/C7H4ClF3O2S/c8-14(12,13)6-3-1-5(2-4-6)7(9,10)11/h1-4H |
InChI key | OZDCZHDOIBUGAJ-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H314 |
预防措施声明 | P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405 |
危险分类 | Skin Corr. 1B |
补充剂危害 | EUH014 |
储存分类代码 | 8A - Combustible, corrosive hazardous materials |
WGK | WGK 3 |
闪点(F) | 230.0 °F |
闪点(C) | > 110 ℃ |
个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
Sigma-Aldrich