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[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

1,1′-双(二-环己基膦基)二茂铁二氯化钯

品牌
Sigma-Aldrich
CAS
917511-90-1
货号
701998
包装型号
规格纯度
98%
价格
502.08 *本价格含增值税费
促销
服务
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数量
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半岛bd体育手机客户端 名称:
917511-90-1
[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)
PdCl 2(dcypf)
1,1′-双(二-环己基膦基)二茂铁二氯化钯
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:

  • α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
  • Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2group and arylboronic acids.
  • α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式 C34H52Cl2FeP2Pd
分子量 755.90
MDL编号 MFCD11656081
PubChem化学物质编号 329762337

半岛bd体育手机客户端 性质

质量水平 100
测定 98%
形式 powder
reaction suitability core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp 294-300 ℃
储存温度 ?20℃
SMILES string [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
InChI 1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
InChI key HRAMBTUEZQOQRK-UHFFFAOYSA-L

安全信息

储存分类代码 13 - Non Combustible Solids
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable
个人防护装备 Eyeshields, Gloves, type N95 (US)

Sigma-Aldrich

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