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1-(Bromoacetyl)pyrene

1-(溴乙酰)芘

品牌
Sigma-Aldrich
CAS
80480-15-5
货号
394408
包装型号
规格纯度
97%
价格
2904.6 *本价格含增值税费
促销
服务
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数量
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半岛bd体育手机客户端 名称:
80480-15-5
1-(Bromoacetyl)pyrene
1-(溴乙酰)芘
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

一般描述

1-(Bromoacetyl)pyrene (BAP) is a pyrene derivative. It has been synthesized by reacting cupric bromide with 1-acetylpyrene. Studies suggest that the introduction of a bromoacetyl chromophoric moiety to pyrene drastically increases the photoinitiating efficiency of pyrenes.

应用

1-(Bromoacetyl)pyrene is suitable for use in the following studies:

  • As an initiator in the bulk polymerization of 2-ethyl-2-oxazoline to generate pyrene labelled poly(2-ethyl-2-oxazoline) (PETOX-py).
  • As a fluorophore in the generation of podand-type fluoroionophores with two pyrene moieties.
  • As a fluorescent labeling agent for the determination of okadaic acid toxin by HPLC with fluorescence detection.
It may also be used in the following studies:
  • As a photoremovable protecting group for carboxylic acids and amino acids.
  • As a photoinitiator in the photopolymerization of styrene with methylmethacrylate.
  • As a reactant in the synthesis of potentially tetradentate pyrene appended ligands.
  • As a derivatizing agent of dialkyl phosphates (DAP) in the HPTLC method of quantitative determination of DAP in fruit juices.

包装

5 g in glass bottle

基本信息

经验(实验)分子式 C18H11BrO
分子量 323.18
MDL编号 MFCD00191839
PubChem化学物质编号 24864593
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
测定 97%
mp 129-131 ℃ (lit.)
SMILES string BrCC(=O)c1ccc2ccc3cccc4ccc1c2c34
InChI 1S/C18H11BrO/c19-10-16(20)14-8-6-13-5-4-11-2-1-3-12-7-9-15(14)18(13)17(11)12/h1-9H,10H2
InChI key KAEDEGFCOPIKKM-UHFFFAOYSA-N

安全信息

象形图 GHS05
警示用语: Danger
危险声明 H314 - H413
预防措施声明 P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类 Aquatic Chronic 4 - Skin Corr. 1B
储存分类代码 8A - Combustible, corrosive hazardous materials
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable
个人防护装备 Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

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