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(S)-3,3′-Dibromo-1,1′-binaphthyl-2,2′-disulfonimide toluene complex

(S)-3,3′-Dibromo-1,1′-binaphthyl-2,2′-disulfonimide toluene complex

品牌
Sigma-Aldrich
货号
790869
包装型号
规格纯度
97%
价格
3717.55 *本价格含增值税费
促销
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数量
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半岛bd体育手机客户端 名称:
( S)-3,3′-Dibromo-1,1′-binaphthyl-2,2′-disulfonimide toluene complex
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

应用

Chiral Bronsted acid amenable to modification at the 3 and 3′ positions.

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

Chiral Sulfonimide as a Br?nsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines

Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

包装

250 mg in glass insert
1 g in glass bottle

基本信息

经验(实验)分子式 (C20H11Br2NO4S2)2· C6H5CH3
分子量 1198.63
MDL编号 MFCD28016339
PubChem化学物质编号 329768245
NACRES NA.22

半岛bd体育手机客户端 性质

质量水平 100
测定 97%
旋光性 [α]22/D +133°, c = 0.5% in chloroform
reaction suitability reaction type: Aldol Reaction
reaction type: Allylation
reaction type: Carbonyl/Imine Addition
reaction type: Friedel-Crafts Alkylation
mp 303-308 ℃ (decomposition without melting)
SMILES string Cc1ccccc1.Brc2cc3ccccc3c4-c5c(c(Br)cc6ccccc56)S(=O)(=O)NS(=O)(=O)c24.Brc7cc8ccccc8c9-c%10c(c(Br)cc%11ccccc%10%11)S(=O)(=O)NS(=O)(=O)c79
InChI 1S/2C20H11Br2NO4S2.C7H8/c2*21-15-9-11-5-1-3-7-13(11)17-18-14-8-4-2-6-12(14)10-16(22)20(18)29(26,27)23-28(24,25)19(15)17;1-7-5-3-2-4-6-7/h2*1-10,23H;2-6H,1H3
InChI key WQYRPPIFPJBANM-UHFFFAOYSA-N

Sigma-Aldrich

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