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位置: 首页> 品牌> Sigma-Aldrich> (dppf)Ni(o-tolyl)Cl

(dppf)Ni(o-tolyl)Cl

品牌
Sigma-Aldrich
CAS
1501945-23-8
货号
802948
包装型号
规格纯度
价格
722.33 *本价格含增值税费
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半岛bd体育手机客户端 名称:
1501945-23-8
(dppf)Ni( o-tolyl)Cl
Buchwald Ni Catalyst
半岛bd体育手机客户端 介绍:

半岛bd体育手机客户端 说明

一般描述

(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式 C41H35ClFeNiP2
分子量 739.66
MDL编号 MFCD28411349
PubChem化学物质编号 329768766

半岛bd体育手机客户端 性质

测定 95%
质量水平 100
形式 powder
reaction suitability core: nickel
reagent type: catalyst
mp 173 ℃
储存温度 2-8℃
SMILES string CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe]
InChI 1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1
InChI key LGLPATFHWYLMCO-UHFFFAOYSA-M

安全信息

象形图 GHS08GHS09
警示用语: Danger
危险声明 H317 - H334 - H341 - H350 - H360 - H372 - H410
预防措施声明 P201 - P273 - P280 - P302 + P352 - P308 + P313
危险分类 Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation
储存分类代码 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK WGK 3
闪点(F) Not applicable
闪点(C) Not applicable

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