半岛bd体育手机客户端 说明
应用
ThianthreneS-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFTS-oxide (903981) was demonstrated as the thanthrenation reagent.
其他说明
Site-selective and versatile aromatic C-H functionalization by thianthrenation
Video: Site-selective C-H functionalization by thianthrenation
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法律信息
Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH
基本信息
经验(实验)分子式 | C12H8OS2 |
分子量 | 232.32 |
MDL编号 | MFCD01464038 |
半岛bd体育手机客户端 性质
测定 | ≥95% |
形式 | powder |
储存温度 | 2-8℃ |
InChI | 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H |
InChI key | NYVGTLXTOJKHJN-UHFFFAOYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich