O-(Diphenylphosphinyl)hydroxylamine

半岛bd体育手机客户端 说明

一般描述

O-(Diphenylphosphinyl)hydroxylamine is a general reagent for electrophilic C-amination, which aminates a variety of stable carbanions and Grignard reagents.

应用

O-(Diphenylphosphinyl)hydroxylamine can be used in:

• The preparation oftrans-2-acylaziridines from α, β-unsaturated ketones via amine-catalyzed reaction.
• Synthesis of enantiomerically pure α, β-diamino acids by stereoselective amination of chiral enolates.
• The conversion of carbanions into corresponding primary amines.

基本信息

经验(实验)分子式	C12H12NO2P
分子量	233.20
MDL编号	MFCD12755701
PubChem化学物质编号	329763105
NACRES	NA.22

半岛bd体育手机客户端 性质

质量水平	100
测定	≥90% (HPLC)
储存温度	2-8℃
SMILES string	NOP(=O)(c1ccccc1)c2ccccc2
InChI	1S/C12H12NO2P/c13-15-16(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,13H2
InChI key	SJECIYLGISUNRO-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable