半岛bd体育手机客户端 说明
一般描述
4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.
应用
次氯酸盐/亚溴酸盐-硝基氧氧化体系的循环催化剂,该体系用于醇转化生成醛、酮和羧酸。它避开了催化或化学计量重金属氧化剂的使用。
4-Hydroxy-TEMPO benzoate was employed as spin probe to investigate the mechanism of synthesis of SBA-15 and to evaluate its surface properties and pore structure by electron paramagnetic resonance spectroscopy (EPR). It was also used for the functionalization of various polydienes (polybutadiene and polyisoprene). Functionalized polydienes were analyzed by gel permeation chromatography.
包装
1 g in glass bottle
基本信息
经验(实验)分子式 | C16H22NO3 |
分子量 | 276.35 |
Beilstein | 1431263 |
MDL编号 | MFCD00075563 |
PubChem化学物质编号 | 24863101 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
测定 | 97% |
mp | 99-101 ℃ (lit.) |
SMILES string | CC1(C)CC(CC(C)(C)N1[O])OC(=O)c2ccccc2 |
InChI | 1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3 |
InChI key | MJEDTBDGYVATPI-UHFFFAOYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |
Sigma-Aldrich