半岛bd体育手机客户端 说明
一般描述
1-Vinyl cyclohexanol, also known as 1-vinyl-1-cyclohexanol, is a tertiary allylic alcohol. It can be synthesized from cyclohexanone and vinyl chloride. It can undergo transition-metal-free tandem allylic borylation in the presence of B2pin [bis(pinacolato)diboron], Cs2CO3, THF and MeOH to yield triborated product. Pd-fullerite catalysts have been prepared which effectively catalyzes the hydrogenation of 1-ethynyl-1-cyclohexanol to 1-vinyl-1-cyclohexanol.
应用
1-Vinyl cyclohexanol may be used to synthesize:
包装
5 g in glass bottle
基本信息
线性分子式 | H2C=CHC6H10OH |
分子量 | 126.20 |
EC 号 | 217-718-7 |
MDL编号 | MFCD01734994 |
PubChem化学物质编号 | 24879518 |
NACRES | NA.22 |
半岛bd体育手机客户端 性质
质量水平 | 100 |
测定 | 97% |
折射率 | n
|
bp | 74 ℃/19 mmHg (lit.) |
密度 | 0.942 g/mL at 25 ℃ (lit.) |
SMILES string | OC1(CCCCC1)C=C |
InChI | 1S/C8H14O/c1-2-8(9)6-4-3-5-7-8/h2,9H,1,3-7H2 |
InChI key | ZXKHOVDDJMJXQP-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 158.0 °F - closed cup |
闪点(C) | 70 ℃ - closed cup |
个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
Sigma-Aldrich