(1<I>S</I>)-7,7-二甲基-2-氧代二环[2.2.1]庚烷-1-甲酸

半岛bd体育手机客户端名称：

40724-67-2
(1S)-(+)-Ketopinic acid
(1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
(1S)-(+)-酮基蒎酸
(1S)-7,7-二甲基-2-氧代二环[2.2.1]庚烷-1-甲酸

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

一般描述

(1S)-(+)-Ketopinic acid is a chiral ketone.

应用

用于制备新型手性噁唑烷酮辅助剂和酮基蒎酸衍生聚合物，该聚合物可用于胺的去外消旋化。合成纯手性 2,10-莰烷二醇的原料。用于生成手性席夫碱前体，以制备二乙基 (S)-α-氨基-α-烷基膦酸酯。
(1S)-(+)-Ketopinic acid may be used to prepare:

Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.
A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.
A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.

包装

1 g in glass bottle

基本信息

半岛bd体育手机客户端性质

测定	99%
旋光性	[α]23/D +58°, c = 1 in chloroform
mp	237-239 ℃ (lit.)
SMILES string	CC1(C)C2CCC1(C(O)=O)C(=O)C2
InChI	1S/C10H14O3/c1-9(2)6-3-4-10(9,8(12)13)7(11)5-6/h6H,3-5H2,1-2H3,(H,12,13)/t6-,10+/m1/s1
InChI key	WDODWBQJVMBHCO-LDWIPMOCSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves