(R,R)-(-)-N,N′-二甲基-1,2-二氨基环己烷

(R,R)-(-)-N,N′-二甲基-1,2-环己二胺

品牌

Sigma-Aldrich

CAS

68737-65-5

货号

671274

包装型号

1 G, ≥97.0% (GC)

规格纯度

≥97.0% (GC)

价格

330.6 元 *本价格含增值税费

促销

数量

- +

半岛bd体育手机客户端名称：

68737-65-5
( R, R)-(-)- N, N′-Dimethyl-1,2-cyclohexanediamine
trans-1,2-Bis(methylamino)cyclohexane
( R, R)-(-)- N, N′-Dimethyl-1,2-diaminocyclohexane
( R, R)-(-)- N, N′-二甲基-1,2-环己二胺
( R, R)-(-)- N, N′-二甲基-1,2-二氨基环己烷
反式-1,2-双(甲氨基)环己烷

半岛bd体育手机客户端介绍：

半岛bd体育手机客户端说明

一般描述

(R,R)-(-)-N,N′-Dimethyl-1,2-cyclohexanediamine is aN,N′-dimethylated derivative of enantiopure 1,2-diaminocyclohexane. It can be formed during the hydrolysis of (R_3a,R_7a)-1,3-(dimethyl)-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide using HCl-methanol.

应用

(R,R)-(?)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:

As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.
In one of the key synthetic steps for the preparation of tricyclic γ-secretase modulators.
To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.

包装

1 g in glass bottle

基本信息

经验(实验)分子式	C₈H₁₈N₂
分子量	142.24
MDL编号	MFCD00671527
PubChem化学物质编号	24885095
NACRES	NA.22

半岛bd体育手机客户端性质

测定	≥97.0% (GC)
旋光性	[α]/D -145±5°, c = 4.47 in chloroform
mp	39-44 ℃
储存温度	2-8℃
SMILES string	CN[C@@H]1CCCC[C@H]1NC
InChI	1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1
InChI key	JRHPOFJADXHYBR-HTQZYQBOSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H302 - H314
预防措施声明	P270 - P280 - P301 + P312 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码	8A - Combustible, corrosive hazardous materials
WGK	WGK 3
闪点(F)	165.2 °F - closed cup
闪点(C)	74 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter