应用
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.

基本信息

MDL
MFCD00011631

EINECS
245-178-2

分子式
C₆H₁₆AlNaO₄

分子量
202.16

闪点
4°(39°F)

密度
1.020

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Viscous liquid

溶解性
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.

Merck
14,8565

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H260-H303-H332-H314-H318-H361-H336-H373-H304
Highly flammable liquid and vapour.In contact with water releases flammable gases which may ignite spontaneously.May be harmful if swallowed.Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.Suspected of damaging fertility or the unborn child.May cause drowsiness or dizziness.May cause damage to organs through prolonged or repeated exposure.May be fatal if swallowed and enters airways.

Precautionary Statements
P223-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire.Keep away from any possible contact with water, because of violent reaction and possible flash fire.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.3

包装组
I

危险类别
11-14/15-20-34-48/20-63-65
Highly flammable.Reacts violently with water, liberating extremely flammable gases.Harmful by inhalation.Causes burns.Harmful: danger of serious damage to health by prolonged exposure through inhalation.Possible risk of harm to the unborn child.Harmful: may cause lung damage if swallowed.

安全等级
4-7/8-9-16-20-23-26-30-33-36/37/39-43-45-60
Keep away from living quarters.Keep container tightly closed and dry.Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Take precautionary measures against static discharges.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是