应用
This compound named Samarium(III) chloride has few practical applications but is used in laboratories for research on new compounds of samarium. Samarium(III) chloride is used for the preparation of samarium metal, which has a variety of uses, notably in magnets. Anhydrous SmCl3 is mixed with sodium chloride or calcium chloride to give a low melting point eutectic mixture. Electrolysis of this molten salt solution gives the free metal. Samarium(III) chloride can also be used as a starting point for the preparation of other samarium salts. The anhydrous chloride is used to prepare organometallic compounds of samarium, such as bis(pentamethylcyclopentadienyl)alkylsamarium(III) complexes.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents. Hygroscopic.

基本信息

MDL
MFCD00011235

EINECS
233-797-0

分子式
SmCl₃

分子量
256.71

熔点
678°

沸点
dec.

密度
4.46

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Powder, Ampouled under argon

溶解性
It is soluble in water.

Merck
14,8347

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
VP2625000

TSCA
是