应用
Samarium(III) chloride hydrate is used for the preparation of samarium metal, which finds use as magnets. It is combined with sodium chloride to get a low melting point eutectic mixture. Further, it serves as a precursor for the preparation of other samarium salts and bis(pentamethylcyclopentadienyl)alkylsamarium(III) complexes. In addition, it serves as a catalyst for hydrogenation and hydrosilylation of alkenes.
备注
Hygroscopic. Incompatible with strong oxidizing agents.
基本信息
MDL
MFCD00011235
EINECS
233-797-0
分子式
SmCl3?xH2O
分子量
256.71(anhy)
熔点
110° -5H{2}O
灵敏度
Hygroscopic. Ambient temperatures.
形态
Crystalline Aggregates
溶解性
Soluble in water and pyridine.
Merck
14,8347
GHS危害和防范说明
GHS符号
Hazard Statements
H303-H315-H319-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险类别
36/37/38
Irritating to eyes, respiratory system and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
TSCA
是