应用
Potassium tricyanomethanide is a precursor used for the preparation of dicyano ketene aminals. It reacts with amines to prepare alkyl ammonium tricyanomethanide. Further, it is involved in the preparation of tricyanomethanide-bridged binuclear organometallic complexes such as Cp(dppe)FeC(CN)₃and Cp(PPh₃)₂RuC(CN)₃. It is used as starting material utilized in the preparation of 5-Amino-3-bromo-1-(tert-butyl)-1H-pyrazole-4-carbonitrile, which undergoes sandmeyer reaction to get the corresponding diaminopyrazole, 5-amino-3-aryl-1-(tert-butyl)-1H-pyrazole-4-carboxamides.

备注
Incompatible with strong oxidizing agents, acids and ammonia.

基本信息

MDL
MFCD00058850

分子式
C₄KN₃

分子量
129.16

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H300-H310-H330
Fatal if swallowed.Fatal in contact with skin.Fatal if inhaled.

Precautionary Statements
P301+P310a-P304+P340-P320-P330-P405-P501a
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Specific treatment is urgent (see label).Rinse mouth.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
II

危险类别
23/24/25
Toxic by inhalation, in contact with skin and if swallowed.

安全等级
4-9-20-27-36/37-45-60
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.Take off immediately all contaminated clothing.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

TSCA
否