应用
1,2,3,4,5-Pentamethylcyclopentadiene serves as a precursor to the ligand 1,2,3,4,5-pentamethylcyclopentadienyl. It is used as a growth modifier chemical, during metal organic chemical vapor deposition of iron from iron pentacarbonyl. It is used as a ligand in "one-pot" iridium-catalyzed transformation of alcohols to amides. Further, it acts as an electron mediator in the regeneration process of nicotinamide adenine dinucleotide. In addition to this, it undergoes radical cation catalyzed cycloaddition reaction with allenes to get Diels-Alder product.

备注
Light sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00001354

EINECS
223-743-4

分子式
C₁₀H₁₆

分子量
136.24

沸点
57-58°/13mm

闪点
44°(111°F)

密度
0.870

折射率
1.4740

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Miscible with methanol. dichloromethane and ethyl acetate. Slightly miscible with water.

Beilstein
1849832

GHS危害和防范说明

GHS符号

Hazard Statements
H226
Flammable liquid and vapour.

Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10
Flammable.

安全等级
43-60
In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')This material and its container must be disposed of as hazardous waste

TSCA
否