应用
Lithium tert-butoxide is a mild base used in organic synthesis. It is involved in the alfa-alkylation reaction of ketones with primary alcohols. It is utilized as a catalyst in the reduction of ketones to the corresponding secondary alcohols. It acts as lithium source utilized in the preparation of Li_xTi_yO_{zthin films. Further, it is used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity.}

备注
Moisture sensitive. Incompatible with acids, water, oxidizing agents, reducing agents, oxygen, alcohols, chlorinated solvents and halogens.

基本信息

MDL
MFCD00050479

EINECS
217-611-5

分子式
C₄H₉LiO

分子量
80.06

熔点
ca 150° dec.

灵敏度
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Powder

溶解性
Soluble in toluene, hexane, tetrahydrofuran and methyl tert-butyl ether.

Beilstein
3620018

GHS危害和防范说明

GHS符号

Hazard Statements
H251-H302-H314
Self-heating: may catch fire.Harmful if swallowed.Causes severe skin burns and eye damage.

Precautionary Statements
P210-P280-P305+P351+P338-P310-P370+P378i-P402+P404
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.In case of fire: Use for extinction: Fire-extinguishing powder.Store in a dry place. Store in a closed container.

安全信息

危险等级
4.1

包装组
II

危险类别
11-14-22-34
Highly flammable.Reacts violently with water.Harmful if swallowed.Causes burns.

安全等级
8-16-26-30-36/37/39-45-60
Keep container dry.Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
UB8520000

TSCA
是