应用
1,3-Dithiane is used in umpolung reactions such as the Corey-Seebach reaction. It acts as a reagent for the deoxygenation of sulfoxides to their corresponding sulfides. Further, it is used as a protecting group for carbonyl compounds used in organic synthesis. It serves as a useful labeled synthon. In addition to this, it is used in the preparation of 2-ethyl-[1,3]dithiane.
备注
Hygroscopic. Incompatible with strong bases and strong oxidizing agents.
基本信息
MDL
MFCD00006654
EINECS
208-006-7
分子式
C4H8S2
分子量
120.24
熔点
52-55°
沸点
207-208°
闪点
90°(194°F)
灵敏度
Ambient temperatures.
形态
Crystalline powder
溶解性
Soluble in benzene, ether, chloroform and terahydrofuran. Slightly soluble in water.
Beilstein
102534
安全信息
RTECS
JO5070000
TSCA
否
阿法埃莎