应用
Diisopropyl azodicarboxylate is used as an important reagent in the production of many organic compounds. It is used in association with triphenyl phosphine in Mitsunobu reaction of alcohols, acids and amides. It acts as reactant in the preparation of chromenes resembling classical cannabinoids, norbornene-based guanidine-rich polymers and acceptor-donor-acceptor organic dyes.

备注
Store in cool place. Light sensitive. Incompatible with strong oxidizing agents, strong bases, alcohols and metallic salts. Decomposes violently at or above: 100⁰C.

基本信息

MDL
MFCD00008875

EINECS
219-502-8

分子式
(CH₃)₂CHO₂C-N=N-CO₂CH(CH₃)₂

分子量
202.21

熔点
3-5°

沸点
74-75°/0.3mm

闪点
160°(320°F)

密度
1.027

折射率
1.4200

灵敏度
Keep Cold. Light Sensitive.

溶解性
Immiscible with water.

Beilstein
1912326

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335-H401-H411
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
36/37/38-51/53
Irritating to eyes, respiratory system and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-37-57-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否