应用
2,3-Dihydrofuran is a versatile reagent used in lanthanide-catalyzed Diels-Alder reactions with 2-pyrones and in Rh(II)-stabilized cycloadditions with vinylcarbenoids. It is applied for alkylation by active methylene compounds, catalyzed by trans-Dichlorobis(triphenyl?-phosphine)?-palladium(II). It is also used in the preparation of biologically active compounds such as antitumor agents.
备注
Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Protect from heat. Keep it refrigerated.
基本信息
MDL
MFCD00003205
EINECS
214-747-7
分子式
C4H6O
分子量
70.09
沸点
54-55°
闪点
-24°(-11°F)
密度
0.927
折射率
1.4245
灵敏度
Keep Cold.
形态
Liquid
溶解性
Soluble in water at 20°C, 20g/L and chloroform.
Beilstein
103168
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H302-H319
Highly flammable liquid and vapour.Harmful if swallowed.Causes serious eye irritation.
Precautionary Statements
P210-P280a-P240-P303+P361+P353-P305+P351+P338-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
II
危险类别
11-19-22-36
Highly flammable.May form explosive peroxides.Harmful if swallowed.Irritating to eyes.
安全等级
9-16-26-33-36
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing.
欧盟危险品标志
TSCA
是
阿法埃莎