应用
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive.

基本信息

MDL
MFCD00013313

分子式
NiCl₂[(C₆H₅)₂PCH₂CH₂P(C₆H₅)₂]

分子量
528.02

熔点
263-265°

灵敏度
Ambient temperatures.

形态
Orange-red to brown powder

溶解性
Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332-H315-H319-H317-H351-H335
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction.Suspected of causing cancer.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/37/38-40-43
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.Limited evidence of a carcinogenic effect.May cause sensitization by skin contact.

安全等级
9-26-36/37-60
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否