应用
(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.

备注
Store in a cool, dry place in a tightly sealed container. Air and moisture stable.

基本信息

MDL
MFCD00009884

EINECS
238-947-9

分子式
C₇H₇RhO₄

分子量
258.04

熔点
144-147° subl.

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in acetone

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H301-H319-H317-H412
Flammable solid.Toxic if swallowed.Causes serious eye irritation.May cause an allergic skin reaction.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P210-P261-P301+P310a-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Avoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
11-25-36-43-53
Highly flammable.Toxic if swallowed.Irritating to eyes.May cause sensitization by skin contact.May cause long-term adverse effects in the aquatic environment.

安全等级
20-24-26-37-45-61
When using do not eat or drink.Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
否