应用
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

备注
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.

基本信息

MDL
MFCD00130127

分子式
C₁₃H₁₃IO₈

分子量
424.15

熔点
130-132° dec.

灵敏度
Store under Argon. Store at -20°C. Moisture Sensitive. Air Sensitive. Light Sensitive.

形态
Solid

溶解性
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Beilstein
4548207

Merck
14,2933

GHS危害和防范说明

GHS符号

Hazard Statements
H272-H315-H319-H335
May intensify fire; oxidizer.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P221-P210a-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.Keep away from heat. - No smoking.Keep/Store away from clothing/combustible materials.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
5.1

包装组
III

危险类别
8-36/37/38-44
Contact with combustible material may cause fire.Irritating to eyes, respiratory system and skin.Risk of explosion if heated under confinement.

安全等级
17-26-37
Keep away from combustible material.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

欧盟危险品标志

TSCA
否