应用
Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. It is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

备注
Air, light and moisture sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00058902

EINECS
215-072-0

分子式
C₁₆H₂₄Ni

分子量
275.06

熔点
60° dec.

灵敏度
Air Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Powder, Packaged under argon

溶解性
Soluble in benzene, toluene, terahydrofuran, ether, dimethyl formamide, hexamethylphosphoramide, N-methylpyrrolidinone. Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H334-H317-H350
Flammable solid.May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause an allergic skin reaction.May cause cancer.

Precautionary Statements
P210-P284-P201-P261-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear respiratory protection.Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
II

危险类别
45-11-43
May cause cancer.Highly flammable.May cause sensitization by skin contact.

安全等级
53-24-37-45-60
Avoid exposure - obtain special instructions before use.Avoid contact with skin.Avoid contact with skin.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
QR6135000

TSCA
否